User:Jaime Prilusky/ChiLe - Revision history

Jaime Prilusky at 08:59, 1 October 2013

Jaime Prilusky — Tue, 01 Oct 2013 08:59:36 GMT

←Older revision		Revision as of 08:59, 1 October 2013
Line 1:		Line 1:
-	== S<sub>N</sub>1-Substitution of Cl<sup>-</sup> and ''tert''-Butanol ==	+	==S<sub>N</sub>1-Substitution of Cl<sup>-</sup> and ''tert''-Butanol ==
-	<~~Structure~~ load='SN1_animation3d.xyz.gz' size='400' ~~frame='true' align~~='right' caption='' scene='' />	+	<StructureSection load='SN1_animation3d.xyz.gz' size='400' side='right' caption='' scene=''>
-		+
	In general, SN1 substitution can take place when a stable carbocation can be formed. If not, the reaction follows the SN2 mechanism.		In general, SN1 substitution can take place when a stable carbocation can be formed. If not, the reaction follows the SN2 mechanism.
	The SN1 <jmol><jmolLink><script>anim mode once; frame range 1 10; delay 0.5; frame play</script><text>reaction starts</text></jmolLink></jmol> with the removement of a hydroxide-ion out of the molecule, in this case tert-Butanol. By this, a positively charged carbocation with a planar geometry is formed. This step is also the rate-determing step because it is the slowest step in this reaction.		The SN1 <jmol><jmolLink><script>anim mode once; frame range 1 10; delay 0.5; frame play</script><text>reaction starts</text></jmolLink></jmol> with the removement of a hydroxide-ion out of the molecule, in this case tert-Butanol. By this, a positively charged carbocation with a planar geometry is formed. This step is also the rate-determing step because it is the slowest step in this reaction.
Line 19:		Line 18:
	<jmolButton><script>if(_animating);anim off;else;frame play;endif</script><text>Toggle animation</text></jmolButton>		<jmolButton><script>if(_animating);anim off;else;frame play;endif</script><text>Toggle animation</text></jmolButton>
	</jmol>		</jmol>
-		+	</StructureSection>
-	~~{{Clear}}~~	+
	This demo was adapted from http://www.chemieunterricht-interaktiv.de/en/animations/sn1_substutition/sn1_substitution_3d.html by Dr. V. Pietzner, part of the ChiLe project		This demo was adapted from http://www.chemieunterricht-interaktiv.de/en/animations/sn1_substutition/sn1_substitution_3d.html by Dr. V. Pietzner, part of the ChiLe project

Jaime Prilusky at 13:22, 18 April 2013

Jaime Prilusky — Thu, 18 Apr 2013 13:22:50 GMT

←Older revision		Revision as of 13:22, 18 April 2013
Line 6:		Line 6:
	In the <jmol><jmolLink><script>anim mode once; frame range 11 20; delay 0.5; frame play</script><text>second step</text></jmolLink></jmol>, the haloanion bound to the carbocation, and a neutral haloalkane is formed. With this step, the hydroxy-substituent is replaced by a halogen-substituent.		In the <jmol><jmolLink><script>anim mode once; frame range 11 20; delay 0.5; frame play</script><text>second step</text></jmolLink></jmol>, the haloanion bound to the carbocation, and a neutral haloalkane is formed. With this step, the hydroxy-substituent is replaced by a halogen-substituent.

-	<!--
-	<jmol><jmolLink><script>frame 1</script><text>First</text></jmolLink></jmol>

	<jmol>		<jmol>
Line 22:		Line 20:
	</jmol>		</jmol>

-	-->
	{{Clear}}		{{Clear}}
	This demo was adapted from http://www.chemieunterricht-interaktiv.de/en/animations/sn1_substutition/sn1_substitution_3d.html by Dr. V. Pietzner, part of the ChiLe project		This demo was adapted from http://www.chemieunterricht-interaktiv.de/en/animations/sn1_substutition/sn1_substitution_3d.html by Dr. V. Pietzner, part of the ChiLe project

Jaime Prilusky at 13:19, 18 April 2013

Jaime Prilusky — Thu, 18 Apr 2013 13:19:14 GMT

←Older revision		Revision as of 13:19, 18 April 2013
Line 3:		Line 3:

	In general, SN1 substitution can take place when a stable carbocation can be formed. If not, the reaction follows the SN2 mechanism.		In general, SN1 substitution can take place when a stable carbocation can be formed. If not, the reaction follows the SN2 mechanism.
-	The SN1 <jmol><jmolLink><script>anim mode once; frame range 1 10; delay 0.5; ~~anim on~~</script><text>reaction starts</text></jmolLink></jmol> with the removement of a hydroxide-ion out of the molecule, in this case tert-Butanol. By this, a positively charged carbocation with a planar geometry is formed. This step is also the rate-determing step because it is the slowest step in this reaction.	+	The SN1 <jmol><jmolLink><script>anim mode once; frame range 1 10; delay 0.5; frame play</script><text>reaction starts</text></jmolLink></jmol> with the removement of a hydroxide-ion out of the molecule, in this case tert-Butanol. By this, a positively charged carbocation with a planar geometry is formed. This step is also the rate-determing step because it is the slowest step in this reaction.
-	In the <jmol><jmolLink><script>anim mode once; frame range 11 20; delay 0.5; ~~anim on~~</script><text>second step</text></jmolLink></jmol>, the haloanion bound to the carbocation, and a neutral haloalkane is formed. With this step, the hydroxy-substituent is replaced by a halogen-substituent.	+	In the <jmol><jmolLink><script>anim mode once; frame range 11 20; delay 0.5; frame play</script><text>second step</text></jmolLink></jmol>, the haloanion bound to the carbocation, and a neutral haloalkane is formed. With this step, the hydroxy-substituent is replaced by a halogen-substituent.

	<!--		<!--

Jaime Prilusky at 13:17, 18 April 2013

Jaime Prilusky — Thu, 18 Apr 2013 13:17:59 GMT

←Older revision		Revision as of 13:17, 18 April 2013
Line 3:		Line 3:

	In general, SN1 substitution can take place when a stable carbocation can be formed. If not, the reaction follows the SN2 mechanism.		In general, SN1 substitution can take place when a stable carbocation can be formed. If not, the reaction follows the SN2 mechanism.
-	The SN1 <jmol><jmolLink><script>anim mode once; frame 1 10; delay 0.5; anim on</script><text>reaction starts</text></jmolLink></jmol> with the removement of a hydroxide-ion out of the molecule, in this case tert-Butanol. By this, a positively charged carbocation with a planar geometry is formed. This step is also the rate-determing step because it is the slowest step in this reaction.	+	The SN1 <jmol><jmolLink><script>anim mode once; frame range 1 10; delay 0.5; anim on</script><text>reaction starts</text></jmolLink></jmol> with the removement of a hydroxide-ion out of the molecule, in this case tert-Butanol. By this, a positively charged carbocation with a planar geometry is formed. This step is also the rate-determing step because it is the slowest step in this reaction.
-	In the <jmol><jmolLink><script>anim mode once; frame 11 20; delay 0.5; anim on</script><text>second step</text></jmolLink></jmol>, the haloanion bound to the carbocation, and a neutral haloalkane is formed. With this step, the hydroxy-substituent is replaced by a halogen-substituent.	+	In the <jmol><jmolLink><script>anim mode once; frame range 11 20; delay 0.5; anim on</script><text>second step</text></jmolLink></jmol>, the haloanion bound to the carbocation, and a neutral haloalkane is formed. With this step, the hydroxy-substituent is replaced by a halogen-substituent.

	<!--		<!--

Jaime Prilusky at 13:16, 18 April 2013

Jaime Prilusky — Thu, 18 Apr 2013 13:16:59 GMT

←Older revision		Revision as of 13:16, 18 April 2013
Line 4:		Line 4:
	In general, SN1 substitution can take place when a stable carbocation can be formed. If not, the reaction follows the SN2 mechanism.		In general, SN1 substitution can take place when a stable carbocation can be formed. If not, the reaction follows the SN2 mechanism.
	The SN1 <jmol><jmolLink><script>anim mode once; frame 1 10; delay 0.5; anim on</script><text>reaction starts</text></jmolLink></jmol> with the removement of a hydroxide-ion out of the molecule, in this case tert-Butanol. By this, a positively charged carbocation with a planar geometry is formed. This step is also the rate-determing step because it is the slowest step in this reaction.		The SN1 <jmol><jmolLink><script>anim mode once; frame 1 10; delay 0.5; anim on</script><text>reaction starts</text></jmolLink></jmol> with the removement of a hydroxide-ion out of the molecule, in this case tert-Butanol. By this, a positively charged carbocation with a planar geometry is formed. This step is also the rate-determing step because it is the slowest step in this reaction.
-	In the <jmol><jmolLink><script></script><text>second step</text></jmolLink></jmol>, the haloanion bound to the carbocation, and a neutral haloalkane is formed. With this step, the hydroxy-substituent is replaced by a halogen-substituent.	+	In the <jmol><jmolLink><script>anim mode once; frame 11 20; delay 0.5; anim on</script><text>second step</text></jmolLink></jmol>, the haloanion bound to the carbocation, and a neutral haloalkane is formed. With this step, the hydroxy-substituent is replaced by a halogen-substituent.

	<!--		<!--

Jaime Prilusky at 13:16, 18 April 2013

Jaime Prilusky — Thu, 18 Apr 2013 13:16:18 GMT

←Older revision		Revision as of 13:16, 18 April 2013
Line 3:		Line 3:

	In general, SN1 substitution can take place when a stable carbocation can be formed. If not, the reaction follows the SN2 mechanism.		In general, SN1 substitution can take place when a stable carbocation can be formed. If not, the reaction follows the SN2 mechanism.
-	The SN1 <jmol><jmolLink><script></script><text>reaction starts</text></jmolLink></jmol> with the removement of a hydroxide-ion out of the molecule, in this case tert-Butanol. By this, a positively charged carbocation with a planar geometry is formed. This step is also the rate-determing step because it is the slowest step in this reaction.	+	The SN1 <jmol><jmolLink><script>anim mode once; frame 1 10; delay 0.5; anim on</script><text>reaction starts</text></jmolLink></jmol> with the removement of a hydroxide-ion out of the molecule, in this case tert-Butanol. By this, a positively charged carbocation with a planar geometry is formed. This step is also the rate-determing step because it is the slowest step in this reaction.
	In the <jmol><jmolLink><script></script><text>second step</text></jmolLink></jmol>, the haloanion bound to the carbocation, and a neutral haloalkane is formed. With this step, the hydroxy-substituent is replaced by a halogen-substituent.		In the <jmol><jmolLink><script></script><text>second step</text></jmolLink></jmol>, the haloanion bound to the carbocation, and a neutral haloalkane is formed. With this step, the hydroxy-substituent is replaced by a halogen-substituent.

Line 23:		Line 23:

	-->		-->
-		+	{{Clear}}
	This demo was adapted from http://www.chemieunterricht-interaktiv.de/en/animations/sn1_substutition/sn1_substitution_3d.html by Dr. V. Pietzner, part of the ChiLe project		This demo was adapted from http://www.chemieunterricht-interaktiv.de/en/animations/sn1_substutition/sn1_substitution_3d.html by Dr. V. Pietzner, part of the ChiLe project

Jaime Prilusky at 13:12, 18 April 2013

Jaime Prilusky — Thu, 18 Apr 2013 13:12:30 GMT

←Older revision		Revision as of 13:12, 18 April 2013
Line 1:		Line 1:
	== S<sub>N</sub>1-Substitution of Cl<sup>-</sup> and ''tert''-Butanol ==		== S<sub>N</sub>1-Substitution of Cl<sup>-</sup> and ''tert''-Butanol ==
-	<Structure load='SN1_animation3d.xyz.gz' size='400' frame='true' align='~~center~~' caption='' scene='' />	+	<Structure load='SN1_animation3d.xyz.gz' size='400' frame='true' align='right' caption='' scene='' />
		+
		+	In general, SN1 substitution can take place when a stable carbocation can be formed. If not, the reaction follows the SN2 mechanism.
		+	The SN1 <jmol><jmolLink><script></script><text>reaction starts</text></jmolLink></jmol> with the removement of a hydroxide-ion out of the molecule, in this case tert-Butanol. By this, a positively charged carbocation with a planar geometry is formed. This step is also the rate-determing step because it is the slowest step in this reaction.
		+	In the <jmol><jmolLink><script></script><text>second step</text></jmolLink></jmol>, the haloanion bound to the carbocation, and a neutral haloalkane is formed. With this step, the hydroxy-substituent is replaced by a halogen-substituent.
		+
		+	<!--
		+	<jmol><jmolLink><script>frame 1</script><text>First</text></jmolLink></jmol>

	<jmol>		<jmol>
Line 15:		Line 22:
	</jmol>		</jmol>

-		+	-->

	This demo was adapted from http://www.chemieunterricht-interaktiv.de/en/animations/sn1_substutition/sn1_substitution_3d.html by Dr. V. Pietzner, part of the ChiLe project		This demo was adapted from http://www.chemieunterricht-interaktiv.de/en/animations/sn1_substutition/sn1_substitution_3d.html by Dr. V. Pietzner, part of the ChiLe project

Jaime Prilusky at 12:23, 14 March 2013

Jaime Prilusky — Thu, 14 Mar 2013 12:23:33 GMT

←Older revision		Revision as of 12:23, 14 March 2013
Line 12:		Line 12:
	<jmolButton><script>frame all</script><text>All frames</text></jmolButton>		<jmolButton><script>frame all</script><text>All frames</text></jmolButton>
	<jmolButton><script>animation mode palindrome 0.5 0.2; anim on</script><text>Loop backwards and forward</text></jmolButton>		<jmolButton><script>animation mode palindrome 0.5 0.2; anim on</script><text>Loop backwards and forward</text></jmolButton>
-	<jmolButton><script>if(_animating);anim off;else;~~anim on~~;endif</script><text>Toggle animation</text></jmolButton>	+	<jmolButton><script>if(_animating);anim off;else;frame play;endif</script><text>Toggle animation</text></jmolButton>
	</jmol>		</jmol>

Jaime Prilusky at 09:55, 13 March 2013

Jaime Prilusky — Wed, 13 Mar 2013 09:55:24 GMT

←Older revision		Revision as of 09:55, 13 March 2013
Line 1:		Line 1:
-	== ~~SN1~~-Substitution of Cl- and tert-Butanol ==	+	== S<sub>N</sub>1-Substitution of Cl<sup>-</sup> and ''tert''-Butanol ==
-	<Structure load='SN1_animation3d.xyz.gz' size='400' frame='true' align='center' caption='~~SN1-Substitution of Cl- and tert-Butanol~~' scene='' />	+	<Structure load='SN1_animation3d.xyz.gz' size='400' frame='true' align='center' caption='' scene='' />

	<jmol>		<jmol>

Jaime Prilusky at 09:17, 13 March 2013

Jaime Prilusky — Wed, 13 Mar 2013 09:17:59 GMT

←Older revision		Revision as of 09:17, 13 March 2013
Line 7:		Line 7:
	<jmolButton><script>anim mode once; frame 1; delay 0.5; anim on</script><text>Play</text></jmolButton>		<jmolButton><script>anim mode once; frame 1; delay 0.5; anim on</script><text>Play</text></jmolButton>
	<jmolButton><script>frame next</script><text>Next</text></jmolButton>		<jmolButton><script>frame next</script><text>Next</text></jmolButton>
-	<jmolButton><script>frame all</script><text>All frames</text></jmolButton>
	</jmol>		</jmol>

	<jmol>		<jmol>
-	<jmolButton><script>	+	<jmolButton><script>frame all</script><text>All frames</text></jmolButton>
-	~~anim mode once;~~ frame ~~1; delay 0.5; anim on~~	+	<jmolButton><script>animation mode palindrome 0.5 0.2; anim on</script><text>Loop backwards and forward</text></jmolButton>
-	</script><text>~~Play once~~</text>.	+	<jmolButton><script>if(_animating);anim off;else;anim on;endif</script><text>Toggle animation</text></jmolButton>
-	</jmolButton>	+
-	~~</jmol>~~	+
-	~~<jmol~~>	+
-	<jmolButton>	+
-	<script>animation mode palindrome 0.5 0.2; anim on</script>	+
-	<text>Loop backwards and forward</text>.	+
-	</jmolButton>	+
-	~~</jmol>~~	+
-	~~<jmol~~>	+
-	<jmolButton>	+
-	<script>if(_animating);anim off;else;anim on;endif</script>	+
-	<text>Toggle animation</text>.	+
-	</jmolButton>	+
	</jmol>		</jmol>