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1qj4

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[[Category: oxynitrilase]]
[[Category: oxynitrilase]]
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''Page seeded by [http://ispc.weizmann.ac.il/oca OCA ] on Tue Oct 30 12:32:26 2007''
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''Page seeded by [http://ispc.weizmann.ac.il/oca OCA ] on Tue Oct 30 16:00:04 2007''

Revision as of 13:55, 30 October 2007


1qj4, resolution 1.10Å

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HYDROXYNITRILE-LYASE FROM HEVEA BRASILIENSIS AT ATOMIC RESOLUTION

Overview

The X-ray crystal structure of native hydroxynitrile lyase from Hevea, brasiliensis (Hb-HNL) has been determined at 1.1 A resolution. It refined, to a final R of 11.5% for all data and an Rfree of 14.4%. The favorable, data-to-parameter ratio at atomic resolution made the refinement of, individual anisotropic displacement parameters possible. The data also, allowed a clear distinction of the alternate orientations of all histidine, and the majority of asparagine and glutamine side chains. A number of, hydrogen atoms, including one on the imidazole of the mechanistically, important His-235, became visible as peaks in a difference electron, density map. The structure revealed a discretely disordered sidechain of, Ser-80, which is part of the putative catalytic triad. Analysis of the, ... [(full description)]

About this Structure

1QJ4 is a [Single protein] structure of sequence from [Hevea brasiliensis] with SO4 and GOL as [ligands]. Active as [Gluconate dehydratase], with EC number [4.2.1.39]. Structure known Active Site: CAT. Full crystallographic information is available from [OCA].

Reference

Atomic resolution crystal structure of hydroxynitrile lyase from Hevea brasiliensis., Gruber K, Gugganig M, Wagner UG, Kratky C, Biol Chem. 1999 Jul-Aug;380(7-8):993-1000. PMID:10494852

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