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4e13

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[[Image:4e13.jpg|left|200px]]
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==Substrate-directed dual catalysis of dicarbonyl compounds by diketoreductase==
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<StructureSection load='4e13' size='340' side='right' caption='[[4e13]], [[Resolution|resolution]] 2.08&Aring;' scene=''>
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== Structural highlights ==
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<table><tr><td colspan='2'>[[4e13]] is a 1 chain structure with sequence from [http://en.wikipedia.org/wiki/Acinetobacter_baylyi Acinetobacter baylyi]. Full crystallographic information is available from [http://oca.weizmann.ac.il/oca-bin/ocashort?id=4E13 OCA]. For a <b>guided tour on the structure components</b> use [http://oca.weizmann.ac.il/oca-docs/fgij/fg.htm?mol=4E13 FirstGlance]. <br>
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</td></tr><tr id='ligand'><td class="sblockLbl"><b>[[Ligand|Ligands:]]</b></td><td class="sblockDat"><scene name='pdbligand=1PE:PENTAETHYLENE+GLYCOL'>1PE</scene>, <scene name='pdbligand=GOL:GLYCEROL'>GOL</scene>, <scene name='pdbligand=NAD:NICOTINAMIDE-ADENINE-DINUCLEOTIDE'>NAD</scene>, <scene name='pdbligand=SO4:SULFATE+ION'>SO4</scene></td></tr>
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<tr id='related'><td class="sblockLbl"><b>[[Related_structure|Related:]]</b></td><td class="sblockDat">[[4dyd|4dyd]], [[4e12|4e12]]</td></tr>
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<tr id='resources'><td class="sblockLbl"><b>Resources:</b></td><td class="sblockDat"><span class='plainlinks'>[http://oca.weizmann.ac.il/oca-docs/fgij/fg.htm?mol=4e13 FirstGlance], [http://oca.weizmann.ac.il/oca-bin/ocaids?id=4e13 OCA], [http://www.rcsb.org/pdb/explore.do?structureId=4e13 RCSB], [http://www.ebi.ac.uk/pdbsum/4e13 PDBsum]</span></td></tr>
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</table>
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<div style="background-color:#fffaf0;">
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== Publication Abstract from PubMed ==
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Diketoreductase catalyzes a two-step bioreduction on a dicarbonyl substrate through a novel dual catalysis mode, in which random hydride attack simultaneously forms two mono-carbonyl intermediates, and subsequently distinct catalytic sites are responsible for the reductions of respective carbonyl group of the intermediates to yield the final dihydroxy product.
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{{STRUCTURE_4e13| PDB=4e13 | SCENE= }}
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Dual catalysis mode for the dicarbonyl reduction catalyzed by diketoreductase.,Lu M, Huang Y, White MA, Wu X, Liu N, Cheng X, Chen Y Chem Commun (Camb). 2012 Oct 24;48(92):11352-4. doi: 10.1039/c2cc36334h. PMID:23073461<ref>PMID:23073461</ref>
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===Substrate-directed dual catalysis of dicarbonyl compounds by diketoreductase===
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From MEDLINE&reg;/PubMed&reg;, a database of the U.S. National Library of Medicine.<br>
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</div>
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== References ==
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==About this Structure==
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<references/>
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[[4e13]] is a 1 chain structure with sequence from [http://en.wikipedia.org/wiki/Acinetobacter_baylyi Acinetobacter baylyi]. Full crystallographic information is available from [http://oca.weizmann.ac.il/oca-bin/ocashort?id=4E13 OCA].
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__TOC__
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</StructureSection>
[[Category: Acinetobacter baylyi]]
[[Category: Acinetobacter baylyi]]
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[[Category: Chen, Y.]]
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[[Category: Chen, Y]]
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[[Category: Cheng, X.]]
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[[Category: Cheng, X]]
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[[Category: Huang, Y.]]
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[[Category: Huang, Y]]
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[[Category: Liu, N.]]
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[[Category: Liu, N]]
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[[Category: Lu, M.]]
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[[Category: Lu, M]]
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[[Category: White, M A.]]
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[[Category: White, M A]]
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[[Category: Wu, X.]]
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[[Category: Wu, X]]
[[Category: Nadh]]
[[Category: Nadh]]
[[Category: Oxidoreductase]]
[[Category: Oxidoreductase]]

Revision as of 16:59, 9 December 2014

Substrate-directed dual catalysis of dicarbonyl compounds by diketoreductase

4e13, resolution 2.08Å

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