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2a5p

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|PDB= 2a5p |SIZE=350|CAPTION= <scene name='initialview01'>2a5p</scene>
|PDB= 2a5p |SIZE=350|CAPTION= <scene name='initialview01'>2a5p</scene>
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|LIGAND= <scene name='pdbligand=DA:2&#39;-DEOXYADENOSINE-5&#39;-MONOPHOSPHATE'>DA</scene>, <scene name='pdbligand=DG:2&#39;-DEOXYGUANOSINE-5&#39;-MONOPHOSPHATE'>DG</scene>, <scene name='pdbligand=DI:2&#39;-DEOXYINOSINE-5&#39;-MONOPHOSPHATE'>DI</scene>, <scene name='pdbligand=DT:THYMIDINE-5&#39;-MONOPHOSPHATE'>DT</scene>
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|RELATEDENTRY=[[1eeg|1EEG]], [[1jjp|1JJP]], [[1y8d|1Y8D]], [[1d6d|1D6D]]
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|RESOURCES=<span class='plainlinks'>[http://oca.weizmann.ac.il/oca-docs/fgij/fg.htm?mol=2a5p FirstGlance], [http://oca.weizmann.ac.il/oca-bin/ocaids?id=2a5p OCA], [http://www.ebi.ac.uk/pdbsum/2a5p PDBsum], [http://www.rcsb.org/pdb/explore.do?structureId=2a5p RCSB]</span>
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[[Category: Patel, D J.]]
[[Category: Patel, D J.]]
[[Category: Phan, A T.]]
[[Category: Phan, A T.]]
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[[Category: monomeric parallel-stranded quadruplex; c-myc promoter 3+1 g-tetrad; single nucleotide chain reversal loop; gag triad; gaag loop]]
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[[Category: c-myc promoter 3+1 g-tetrad]]
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[[Category: gaag loop]]
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[[Category: gag triad]]
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[[Category: monomeric parallel-stranded quadruplex]]
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[[Category: single nucleotide chain reversal loop]]
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Revision as of 22:48, 30 March 2008


PDB ID 2a5p

Drag the structure with the mouse to rotate
Ligands: , , ,
Related: 1EEG, 1JJP, 1Y8D, 1D6D


Resources: FirstGlance, OCA, PDBsum, RCSB
Coordinates: save as pdb, mmCIF, xml



Monomeric parallel-stranded DNA tetraplex with snap-back 3+1 3' G-tetrad, single-residue chain reversal loops, GAG triad in the context of GAAG diagonal loop, NMR, 8 struct.


Overview

It has been widely accepted that DNA can adopt other biologically relevant structures beside the Watson-Crick double helix. One recent important example is the guanine-quadruplex (G-quadruplex) structure formed by guanine tracts found in the MYC (or c-myc) promoter region, which regulates the transcription of the MYC oncogene. Stabilization of this G-quadruplex by ligands, such as the cationic porphyrin TMPyP4, decreases the transcriptional level of MYC. Here, we report the first structure of a DNA fragment containing five guanine tracts from this region. An unusual G-quadruplex fold, which was derived from NMR restraints using unambiguous model-independent resonance assignment approaches, involves a core of three stacked guanine tetrads formed by four parallel guanine tracts with all anti guanines and a snapback 3'-end syn guanine. We have determined the structure of the complex formed between this G-quadruplex and TMPyP4. This structural information, combined with details of small-molecule interaction, provides a platform for the design of anticancer drugs targeting multi-guanine-tract sequences that are found in the MYC and other oncogenic promoters, as well as in telomeres.

About this Structure

2A5P is a Protein complex structure of sequences from Homo sapiens. Full crystallographic information is available from OCA.

Reference

Small-molecule interaction with a five-guanine-tract G-quadruplex structure from the human MYC promoter., Phan AT, Kuryavyi V, Gaw HY, Patel DJ, Nat Chem Biol. 2005 Aug;1(3):167-73. Epub 2005 Jul 17. PMID:16408022

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