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470d

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|PDB= 470d |SIZE=350|CAPTION= <scene name='initialview01'>470d</scene>, resolution 1.95&Aring;
|PDB= 470d |SIZE=350|CAPTION= <scene name='initialview01'>470d</scene>, resolution 1.95&Aring;
|SITE=
|SITE=
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|LIGAND= <scene name='pdbligand=MG:MAGNESIUM ION'>MG</scene>
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|LIGAND= <scene name='pdbligand=A44:2&#39;-O-METHYOXYETHYL-ADENOSINE+5&#39;-MONOPHOSPHATE'>A44</scene>, <scene name='pdbligand=C43:2&#39;-O-METHYOXYETHYL-CYTIDINE-5&#39;-MONOPHOSPHATE'>C43</scene>, <scene name='pdbligand=G48:2&#39;-O-METHYOXYETHYL-GUANOSINE-5&#39;-MONOPHOSPHATE'>G48</scene>, <scene name='pdbligand=MG:MAGNESIUM+ION'>MG</scene>, <scene name='pdbligand=U36:2&#39;-O-METHYOXYETHYL-URIDINE-5&#39;-MONOPHOSPHATE'>U36</scene>
|ACTIVITY=
|ACTIVITY=
|GENE=
|GENE=
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|DOMAIN=
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|RELATEDENTRY=
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|RESOURCES=<span class='plainlinks'>[http://oca.weizmann.ac.il/oca-docs/fgij/fg.htm?mol=470d FirstGlance], [http://oca.weizmann.ac.il/oca-bin/ocaids?id=470d OCA], [http://www.ebi.ac.uk/pdbsum/470d PDBsum], [http://www.rcsb.org/pdb/explore.do?structureId=470d RCSB]</span>
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[[Category: Teplova, M.]]
[[Category: Teplova, M.]]
[[Category: Tereshko, V.]]
[[Category: Tereshko, V.]]
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[[Category: MG]]
 
[[Category: 2'-o-(2-methoxyethyl) ribose]]
[[Category: 2'-o-(2-methoxyethyl) ribose]]
[[Category: ribonucleic acid]]
[[Category: ribonucleic acid]]
[[Category: rna dodecamer duplex]]
[[Category: rna dodecamer duplex]]
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''Page seeded by [http://oca.weizmann.ac.il/oca OCA ] on Thu Mar 20 19:08:38 2008''
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''Page seeded by [http://oca.weizmann.ac.il/oca OCA ] on Mon Mar 31 05:37:37 2008''

Revision as of 02:37, 31 March 2008


PDB ID 470d

Drag the structure with the mouse to rotate
, resolution 1.95Å
Ligands: , , , ,
Resources: FirstGlance, OCA, PDBsum, RCSB
Coordinates: save as pdb, mmCIF, xml



CRYSTAL STRUCTURE AND IMPROVED ANTISENSE PROPERTIES OF 2'-O-(2-METHOXYETHYL)-RNA


Overview

2'-O-(2-Methoxyethyl)-RNA (MOE-RNA) is a nucleic acid analog with promising features for antisense applications. Compared with phosphorothioate DNA (PS-DNA), the MOE modification offers improved nuclease resistance, enhanced RNA affinity, improved cellular uptake and intestinal absorption, reduced toxicity and immune stimulation. The crystal structure of a fully modified MOE-RNA dodecamer duplex (CGCGAAUUCGCG) was determined at 1.7 A resolution. In the majority of the MOE substituents, the torsion angle around the ethylene alkyl chain assumes a gauche conformation. The conformational preorganization of the MOE groups is consistent with the improved RNA affinity and the extensive hydration of the substituents could play a role in the improved cellular uptake of MOE-RNA. A specific hydration pattern that bridges substituent and phosphate oxygen atoms in the minor groove of MOE-RNA may explain its high nuclease resistance.

About this Structure

470D is a Protein complex structure of sequences from [1]. Full crystallographic information is available from OCA.

Reference

Crystal structure and improved antisense properties of 2'-O-(2-methoxyethyl)-RNA., Teplova M, Minasov G, Tereshko V, Inamati GB, Cook PD, Manoharan M, Egli M, Nat Struct Biol. 1999 Jun;6(6):535-9. PMID:10360355

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