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1ngl

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|RESOURCES=<span class='plainlinks'>[http://oca.weizmann.ac.il/oca-docs/fgij/fg.htm?mol=1ngl FirstGlance], [http://oca.weizmann.ac.il/oca-bin/ocaids?id=1ngl OCA], [http://www.ebi.ac.uk/pdbsum/1ngl PDBsum], [http://www.rcsb.org/pdb/explore.do?structureId=1ngl RCSB]</span>
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'''HUMAN NEUTROPHIL GELATINASE-ASSOCIATED LIPOCALIN (HNGAL), REGULARISED AVERAGE NMR STRUCTURE'''
'''HUMAN NEUTROPHIL GELATINASE-ASSOCIATED LIPOCALIN (HNGAL), REGULARISED AVERAGE NMR STRUCTURE'''
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[[Category: Tschesche, H.]]
[[Category: Tschesche, H.]]
[[Category: Zoelzer, V.]]
[[Category: Zoelzer, V.]]
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[[Category: lipocalin]]
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[[Category: Lipocalin]]
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[[Category: mmp-9 component]]
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[[Category: Mmp-9 component]]
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[[Category: transport protein]]
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[[Category: Transport protein]]
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Revision as of 23:30, 2 May 2008

Template:STRUCTURE 1ngl

HUMAN NEUTROPHIL GELATINASE-ASSOCIATED LIPOCALIN (HNGAL), REGULARISED AVERAGE NMR STRUCTURE


Overview

Human neutrophil gelatinase-associated lipocalin (HNGAL) is a member of the lipocalin family of extracellular proteins that function as transporters of small, hydrophobic molecules. HNGAL, a component of human blood granulocytes, binds bacterially derived formyl peptides that act as chemotactic agents and induce leukocyte granule discharge. HNGAL also forms a complex with the proenzyme form of matrix metalloproteinase-9 (pro-MMP-9, or progelatinase B) via an intermolecular disulphide bridge. This association allows the subsequent formation of ternary and quaternary metalloproteinase/inhibitor complexes that vary greatly in their metalloproteinase activities. The structure and dynamics of apo-HNGAL have been determined by NMR spectroscopy. Simulated annealing calculations yielded a set of 20 convergent structures with an average backbone RMSD from mean coordinate positions of 0. 79(+/-0.13) A over secondary structure elements. The overall rotational correlation time (13.3 ns) derived from15N relaxation data is consistent with a monomeric protein of the size of HNGAL (179 residues) under the experimental conditions (1.4 mM protein, pH 6.0, 24.5 degrees C). The structure features an eight-stranded antiparallel beta-barrel, typical of the lipocalin family. One end of the barrel is open, providing access to the binding site within the barrel cavity, while the other is closed by a short 310-helix. The free cysteine residue required for association with pro-MMP-9 lies in an inter-strand loop at the closed end of the barrel. The structure provides a detailed model of the ligand-binding site and has led to the proposal of a site for pro-MMP-9 association. Dynamic data correlate well with structural features, which has allowed us to investigate a mechanism by which a cell-surface receptor might distinguish between apo and holo-HNGAL through conformational changes at the open end of the barrel.

About this Structure

1NGL is a Single protein structure of sequence from Homo sapiens. Full crystallographic information is available from OCA.

Reference

The solution structure and dynamics of human neutrophil gelatinase-associated lipocalin., Coles M, Diercks T, Muehlenweg B, Bartsch S, Zolzer V, Tschesche H, Kessler H, J Mol Biol. 1999 May 28;289(1):139-57. PMID:10339412 Page seeded by OCA on Sat May 3 02:30:23 2008

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