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User:Wayne Decatur/mof dev
From Proteopedia
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| - | + | Shown at the right is the building block of the lattice (<scene name='10/1092924/Jarmeu_basics/1'>restore initial scene</scene>). | |
| - | <scene name='10/1092924/Csd_entry_jarmeu_1x1x3_set/3'> | + | When the repeats of this building block are shown connected to others, the lattice appears. Viewing the <scene name='10/1092924/Csd_entry_jarmeu_1x1x3_set/3'>the CSD entry JARMEU as a 1x1x3 set of the metal organic framework</scene> illustrates this.<br/> |
| - | + | When considered this way a beautiful diamondoid structure appears that is a 4-connected network. <br/> | |
The large cavities are visible as the lattice layers onto itself as the view of the structure rotates. <br/> | The large cavities are visible as the lattice layers onto itself as the view of the structure rotates. <br/> | ||
| + | The extensive nature becomes more apparent if we consider more of the lattice. <br/> | ||
<scene name='10/1092924/Csd_entry_jarmeu_1x3x3_plane/2'>The CSD entry JARMEU as a 1x3x3 plane of the metal organic framework</scene>. (Patience required when loading this view.) | <scene name='10/1092924/Csd_entry_jarmeu_1x3x3_plane/2'>The CSD entry JARMEU as a 1x3x3 plane of the metal organic framework</scene>. (Patience required when loading this view.) | ||
Revision as of 18:52, 9 October 2025
A cubic diamond lattice metal-organic framework
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Contents |
Technical Details
The views featuring the 1x1x3 set and the plane were built using the Jmol Crystal Symmetry Explorer to examine CSD Entry: JARMEU.
Reference
- B.F. Hoskins and R. Robson. 1989. Infinite polymeric frameworks consisting of three dimensionally linked rod-like segments. Journal of the American Chemical Society, v111, pg. 5962-5964, |DOI: 10.1021/ja00197a079
See also
A catalytic molybdenum metal-organic framework
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Technical Details
The views featuring the 1x1x3 set and the plane were built using the Jmol Crystal Symmetry Explorer to examine CSD Entry: WUTXUH.
Reference
- Xia Z, Li F, Xu L, Feng P. A stable and highly selective metalloporphyrin based framework for the catalytic oxidation of cyclohexene. Dalton Trans. 2020 Aug 18;49(32):11157-11162. PMID:32744270 doi:10.1039/d0dt01420f
