Cubic Diamond Lattice Metal-Organic Framework

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Current revision (14:14, 13 October 2025) (edit) (undo)
 
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==Background==
==Background==
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Synthesized metal-organic frameworks have been shown to have a wide range of applications, as [[Proteopedia:Hot_News|highlighted three chemists doing seminal work in this field being awarded the Nobel Prize in Chemistry in 2025]].
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Synthesized metal-organic frameworks have been shown to have a wide range of applications. [[Proteopedia:Hot_News|Three chemists who did seminal work in this field were awarded the Nobel Prize in Chemistry in 2025]].
Here the crystal structure of a cubic diamond metal-organic framework is featured; [https://www.ccdc.cam.ac.uk/structures/Search?Ccdcid=JARMEU&DatabaseToSearch=CSD the CSD entry JARMEU]<ref>B.F. Hoskins and R. Robson. 1989. Infinite polymeric frameworks consisting of three dimensionally linked rod-like segments. Journal of the American Chemical Society, v111, pg. 5962-5964, [https://pubs.acs.org/doi/abs/10.1021/ja00197a079 |DOI: 10.1021/ja00197a079]</ref>. <br/>
Here the crystal structure of a cubic diamond metal-organic framework is featured; [https://www.ccdc.cam.ac.uk/structures/Search?Ccdcid=JARMEU&DatabaseToSearch=CSD the CSD entry JARMEU]<ref>B.F. Hoskins and R. Robson. 1989. Infinite polymeric frameworks consisting of three dimensionally linked rod-like segments. Journal of the American Chemical Society, v111, pg. 5962-5964, [https://pubs.acs.org/doi/abs/10.1021/ja00197a079 |DOI: 10.1021/ja00197a079]</ref>. <br/>
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<scene name='10/1092924/Csd_entry_jarmeu_lattice/4'>The CSD entry JARMEU as a 1x4x6 lattice of the metal organic framework</scene>.
<scene name='10/1092924/Csd_entry_jarmeu_lattice/4'>The CSD entry JARMEU as a 1x4x6 lattice of the metal organic framework</scene>.
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<scene name='10/1092924/Csd_entry_jarmeu_lattice/5'>Restrict to only the central cell of the 1x4x6 lattice</scene>.
 
<jmol>
<jmol>
<jmolCheckbox>
<jmolCheckbox>
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<scriptWhenChecked>display all;</scriptWhenChecked>
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<scriptWhenChecked>hide all and not cell=555;</scriptWhenChecked>
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<scriptWhenUnchecked>restrict cell=555;</scriptWhenUnchecked>
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<scriptWhenUnchecked>display all;</scriptWhenUnchecked>
<checked>false</checked>
<checked>false</checked>
<!-- <checked></checked> set it to false or delete it or comment it out as <checked>false</checked> or <checked> </checked>still show as checked-->
<!-- <checked></checked> set it to false or delete it or comment it out as <checked>false</checked> or <checked> </checked>still show as checked-->
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<text>Toggle back on lattice</text>
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<text>Toggle to limit to the key cell vs. the current lattice network framework</text>
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</jmolCheckbox>
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</jmol>
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<jmol>
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<jmolCheckbox>
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<scriptWhenChecked>select all; spacefill on;</scriptWhenChecked>
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<scriptWhenUnchecked>select all; spacefill 0.35; select hydrogen; spacefill 0.25;</scriptWhenUnchecked>
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<checked>false</checked>
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<!-- <checked></checked> set it to false or delete it or comment it out as <checked>false</checked> or <checked> </checked>still show as checked-->
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<text>CPK Spacefll mode</text>
</jmolCheckbox>
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</jmol>
</jmol>

Current revision

A Metal–organic framework structure: the CSD entry JARMEU

Drag the structure with the mouse to rotate

References

  1. ↑ B.F. Hoskins and R. Robson. 1989. Infinite polymeric frameworks consisting of three dimensionally linked rod-like segments. Journal of the American Chemical Society, v111, pg. 5962-5964, |DOI: 10.1021/ja00197a079
  2. ↑ https://www.nobelprize.org/uploads/2025/10/advanced-chemistryprize2025.pdf

See also

Proteopedia Page Contributors and Editors (what is this?)

Wayne Decatur, Eric Martz

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