2q0m

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(New page: 200px<br /><applet load="2q0m" size="350" color="white" frame="true" align="right" spinBox="true" caption="2q0m, resolution 1.70&Aring;" /> '''Tricarbonylmanganese...)
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==Overview==
==Overview==
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The reaction of the new and structurally characterized covalent, {Mn(CO)(3)(H(2)O)(2)}(+)-lysozyme adduct with NiS(4) and NiN(2)S(2), complexes generates binuclear Ni-Mn complexes; relevance to the reactivity, of the protein-bound {Fe(CO)(CN)(2)} intermediate during maturation of, [NiFe] hydrogenases is discussed.
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The reaction of the new and structurally characterized covalent {Mn(CO)(3)(H(2)O)(2)}(+)-lysozyme adduct with NiS(4) and NiN(2)S(2) complexes generates binuclear Ni-Mn complexes; relevance to the reactivity of the protein-bound {Fe(CO)(CN)(2)} intermediate during maturation of [NiFe] hydrogenases is discussed.
==About this Structure==
==About this Structure==
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[[Category: Cavazza, C.]]
[[Category: Cavazza, C.]]
[[Category: Fontecave, M.]]
[[Category: Fontecave, M.]]
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[[Category: Fontecilla-Camps, J.C.]]
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[[Category: Fontecilla-Camps, J C.]]
[[Category: Oudart, Y.]]
[[Category: Oudart, Y.]]
[[Category: Razavet, M.]]
[[Category: Razavet, M.]]
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[[Category: tricarbonyl manganese(i)]]
[[Category: tricarbonyl manganese(i)]]
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''Page seeded by [http://oca.weizmann.ac.il/oca OCA ] on Wed Jan 23 11:43:56 2008''
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''Page seeded by [http://oca.weizmann.ac.il/oca OCA ] on Thu Feb 21 18:34:53 2008''

Revision as of 16:34, 21 February 2008


2q0m, resolution 1.70Å

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Tricarbonylmanganese(I)-lysozyme complex : a structurally characterized organometallic protein

Overview

The reaction of the new and structurally characterized covalent {Mn(CO)(3)(H(2)O)(2)}(+)-lysozyme adduct with NiS(4) and NiN(2)S(2) complexes generates binuclear Ni-Mn complexes; relevance to the reactivity of the protein-bound {Fe(CO)(CN)(2)} intermediate during maturation of [NiFe] hydrogenases is discussed.

About this Structure

2Q0M is a Single protein structure of sequence from Gallus gallus with , , , and as ligands. Active as Lysozyme, with EC number 3.2.1.17 Full crystallographic information is available from OCA.

Reference

Tricarbonylmanganese(I)-lysozyme complex: a structurally characterized organometallic protein., Razavet M, Artero V, Cavazza C, Oudart Y, Lebrun C, Fontecilla-Camps JC, Fontecave M, Chem Commun (Camb). 2007 Jul 19;(27):2805-7. Epub 2007 Jun 11. PMID:17609782

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