1c0n

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|LIGAND= <scene name='pdbligand=ACY:ACETIC+ACID'>ACY</scene>, <scene name='pdbligand=PLP:PYRIDOXAL-5&#39;-PHOSPHATE'>PLP</scene>
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|RESOURCES=<span class='plainlinks'>[http://oca.weizmann.ac.il/oca-docs/fgij/fg.htm?mol=1c0n FirstGlance], [http://oca.weizmann.ac.il/oca-bin/ocaids?id=1c0n OCA], [http://www.ebi.ac.uk/pdbsum/1c0n PDBsum], [http://www.rcsb.org/pdb/explore.do?structureId=1c0n RCSB]</span>
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'''CSDB PROTEIN, NIFS HOMOLOGUE'''
'''CSDB PROTEIN, NIFS HOMOLOGUE'''
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[[Category: Maeda, M.]]
[[Category: Maeda, M.]]
[[Category: Mihara, H.]]
[[Category: Mihara, H.]]
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[[Category: alpha/beta fold]]
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[[Category: Alpha/beta fold]]
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Revision as of 09:11, 2 May 2008

Template:STRUCTURE 1c0n

CSDB PROTEIN, NIFS HOMOLOGUE


Overview

Escherichia coli CsdB, a NifS homologue with a high specificity for L-selenocysteine, is a pyridoxal 5'-phosphate (PLP)-dependent dimeric enzyme that belongs to aminotransferases class V in fold-type I of PLP enzymes and catalyzes the decomposition of L-selenocysteine into selenium and L-alanine. The crystal structure of the enzyme has been determined by the X-ray crystallographic method of multiple isomorphous replacement and refined to an R-factor of 18.7% at 2.8 A resolution. The subunit structure consists of three parts: a large domain of an alpha/beta-fold containing a seven-stranded beta-sheet flanked by seven helices, a small domain containing a four-stranded antiparallel beta-sheet flanked by three alpha-helices, and an N-terminal segment containing two alpha-helices. The overall fold of the subunit is similar to those of the enzymes belonging to the fold-type I family represented by aspartate aminotransferase. However, CsdB has several structural features that are not observed in other families of the enzymes. A remarkable feature is that an alpha-helix in the lobe extending from the small domain to the large domain in one subunit of the dimer interacts with a beta-hairpin loop protruding from the large domain of the other subunit. The extended lobe and the protruded beta-hairpin loop form one side of a limb of each active site in the enzyme. The most striking structural feature of CsdB lies in the location of a putative catalytic residue; the side chain of Cys364 on the extended lobe of one subunit is close enough to interact with the gamma-atom of a modeled substrate in the active site of the subunit. Moreover, His55 from the other subunit is positioned so that it interacts with the gamma- or beta-atom of the substrate and may be involved in the catalytic reaction. This is the first report on three-dimensional structures of NifS homologues.

About this Structure

1C0N is a Single protein structure of sequence from Escherichia coli. Full crystallographic information is available from OCA.

Reference

Structure of a NifS homologue: X-ray structure analysis of CsdB, an Escherichia coli counterpart of mammalian selenocysteine lyase., Fujii T, Maeda M, Mihara H, Kurihara T, Esaki N, Hata Y, Biochemistry. 2000 Feb 15;39(6):1263-73. PMID:10684605 Page seeded by OCA on Fri May 2 12:11:39 2008

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