1r3g

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(New page: 200px<br /><applet load="1r3g" size="450" color="white" frame="true" align="right" spinBox="true" caption="1r3g, resolution 1.16&Aring;" /> '''1.16A X-ray structur...)
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[[Image:1r3g.gif|left|200px]]<br /><applet load="1r3g" size="350" color="white" frame="true" align="right" spinBox="true"
caption="1r3g, resolution 1.16&Aring;" />
caption="1r3g, resolution 1.16&Aring;" />
'''1.16A X-ray structure of the synthetic DNA fragment with the incorporated 2'-O-[(2-Guanidinium)ethyl]-5-methyluridine residues'''<br />
'''1.16A X-ray structure of the synthetic DNA fragment with the incorporated 2'-O-[(2-Guanidinium)ethyl]-5-methyluridine residues'''<br />
==Overview==
==Overview==
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[structure: see text] Oligonucleotides with a novel, 2'-O-[2-(guanidinium)ethyl] (2'-O-GE) modification have been synthesized, using a novel protecting group strategy for the guanidinium group. This, modification enhances the binding affinity of oligonucleotides to RNA as, well as duplex DNA (DeltaT(m) 3.2 degrees C per modification). The 2'-O-GE, modified oligonucleotides exhibited exceptional resistance to nuclease, degradation. The crystal structure of a palindromic duplex formed by a DNA, oligonucleotide with a single 2'-O-GE modification was solved at 1.16 A, resolution.
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[structure: see text] Oligonucleotides with a novel 2'-O-[2-(guanidinium)ethyl] (2'-O-GE) modification have been synthesized using a novel protecting group strategy for the guanidinium group. This modification enhances the binding affinity of oligonucleotides to RNA as well as duplex DNA (DeltaT(m) 3.2 degrees C per modification). The 2'-O-GE modified oligonucleotides exhibited exceptional resistance to nuclease degradation. The crystal structure of a palindromic duplex formed by a DNA oligonucleotide with a single 2'-O-GE modification was solved at 1.16 A resolution.
==About this Structure==
==About this Structure==
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1R3G is a [http://en.wikipedia.org/wiki/Protein_complex Protein complex] structure of sequences from [http://en.wikipedia.org/wiki/ ] with MG as [http://en.wikipedia.org/wiki/ligand ligand]. Full crystallographic information is available from [http://ispc.weizmann.ac.il/oca-bin/ocashort?id=1R3G OCA].
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1R3G is a [http://en.wikipedia.org/wiki/Protein_complex Protein complex] structure of sequences from [http://en.wikipedia.org/wiki/ ] with <scene name='pdbligand=MG:'>MG</scene> as [http://en.wikipedia.org/wiki/ligand ligand]. Full crystallographic information is available from [http://oca.weizmann.ac.il/oca-bin/ocashort?id=1R3G OCA].
==Reference==
==Reference==
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[[Category: Lesnik, E.]]
[[Category: Lesnik, E.]]
[[Category: Manoharan, M.]]
[[Category: Manoharan, M.]]
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[[Category: Prakash, T.P.]]
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[[Category: Prakash, T P.]]
[[Category: Puschl, A.]]
[[Category: Puschl, A.]]
[[Category: Tereshko, V.]]
[[Category: Tereshko, V.]]
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[[Category: dna]]
[[Category: dna]]
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''Page seeded by [http://ispc.weizmann.ac.il/oca OCA ] on Sat Nov 24 22:02:37 2007''
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''Page seeded by [http://oca.weizmann.ac.il/oca OCA ] on Thu Feb 21 14:46:35 2008''

Revision as of 12:46, 21 February 2008


1r3g, resolution 1.16Å

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1.16A X-ray structure of the synthetic DNA fragment with the incorporated 2'-O-[(2-Guanidinium)ethyl]-5-methyluridine residues

Overview

[structure: see text] Oligonucleotides with a novel 2'-O-[2-(guanidinium)ethyl] (2'-O-GE) modification have been synthesized using a novel protecting group strategy for the guanidinium group. This modification enhances the binding affinity of oligonucleotides to RNA as well as duplex DNA (DeltaT(m) 3.2 degrees C per modification). The 2'-O-GE modified oligonucleotides exhibited exceptional resistance to nuclease degradation. The crystal structure of a palindromic duplex formed by a DNA oligonucleotide with a single 2'-O-GE modification was solved at 1.16 A resolution.

About this Structure

1R3G is a Protein complex structure of sequences from [1] with as ligand. Full crystallographic information is available from OCA.

Reference

2'-O-[2-(guanidinium)ethyl]-modified oligonucleotides: stabilizing effect on duplex and triplex structures., Prakash TP, Puschl A, Lesnik E, Mohan V, Tereshko V, Egli M, Manoharan M, Org Lett. 2004 Jun 10;6(12):1971-4. PMID:15176796

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