SN1 reaction
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Jaime Prilusky (Talk | contribs)
(New page: == S<sub>N</sub>1-Substitution of Cl<sup>-</sup> and ''tert''-Butanol == <Structure load='SN1_animation3d.xyz.gz' size='400' frame='true' align='right' caption='' scene='' /> In general, ...)
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Revision as of 12:08, 21 April 2013
SN1-Substitution of Cl- and tert-Butanol
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In general, SN1 substitution can take place when a stable carbocation can be formed. If not, the reaction follows the SN2 mechanism. The SN1 with the removement of a hydroxide-ion out of the molecule, in this case tert-Butanol. By this, a positively charged carbocation with a planar geometry is formed. This step is also the rate-determing step because it is the slowest step in this reaction. In the , the haloanion bound to the carbocation, and a neutral haloalkane is formed. With this step, the hydroxy-substituent is replaced by a halogen-substituent.
This demo was adapted from http://www.chemieunterricht-interaktiv.de/en/animations/sn1_substutition/sn1_substitution_3d.html by Dr. V. Pietzner, part of the ChiLe project
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Joel L. Sussman, Jaime Prilusky, Angel Herraez, Verena Pietzner