2mb3

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{{STRUCTURE_2mb3| PDB=2mb3 | SCENE= }}
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==Solution structure of an intramolecular (3+1) human telomeric G-quadruplex bound to a telomestatin derivative==
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===Solution structure of an intramolecular (3+1) human telomeric G-quadruplex bound to a telomestatin derivative===
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<StructureSection load='2mb3' size='340' side='right' caption='[[2mb3]], [[NMR_Ensembles_of_Models | 10 NMR models]]' scene=''>
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{{ABSTRACT_PUBMED_23909929}}
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== Structural highlights ==
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<table><tr><td colspan='2'>[[2mb3]] is a 1 chain structure. Full experimental information is available from [http://oca.weizmann.ac.il/oca-bin/ocashort?id=2MB3 OCA]. For a <b>guided tour on the structure components</b> use [http://oca.weizmann.ac.il/oca-docs/fgij/fg.htm?mol=2MB3 FirstGlance]. <br>
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</td></tr><tr id='ligand'><td class="sblockLbl"><b>[[Ligand|Ligands:]]</b></td><td class="sblockDat"><scene name='pdbligand=L2H:(12S,27S)-12,27-BIS(4-AMINOBUTYL)-4,30-DIMETHYL-3,7,14,18,22,29-HEXAOXA-11,26,31,32,33,34,35,36-OCTAAZAHEPTACYCLO[26.2.1.1~2,5~.1~6,9~.1~13,16~.1~17,20~.1~21,24~]HEXATRIACONTA-1(30),2(36),4,6(35),8,13(34),15,17(33),19,21(32),23,28(31)-DODECAENE-10,25-DIONE'>L2H</scene></td></tr>
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<tr id='resources'><td class="sblockLbl"><b>Resources:</b></td><td class="sblockDat"><span class='plainlinks'>[http://oca.weizmann.ac.il/oca-docs/fgij/fg.htm?mol=2mb3 FirstGlance], [http://oca.weizmann.ac.il/oca-bin/ocaids?id=2mb3 OCA], [http://www.rcsb.org/pdb/explore.do?structureId=2mb3 RCSB], [http://www.ebi.ac.uk/pdbsum/2mb3 PDBsum]</span></td></tr>
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</table>
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<div style="background-color:#fffaf0;">
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== Publication Abstract from PubMed ==
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Guanine-rich human telomeric DNA can adopt secondary structures known as G-quadruplexes, which can be targeted by small molecules to achieve anticancer effects. So far, the structural information on complexes between human telomeric DNA and ligands is limited to the parallel G-quadruplex conformation, despite the high structural polymorphism of human telomeric G-quadruplexes. No structure has been yet resolved for the complex with telomestatin, one of the most promising G-quadruplex-targeting anticancer drug candidates. Here we present the first high-resolution structure of the complex between an intramolecular (3+1) human telomeric G-quadruplex and a telomestatin derivative, the macrocyclic hexaoxazole L2H2-6M(2)OTD. This compound is observed to interact with the G-quadruplex through pi-stacking and electrostatic interactions. This structural information provides a platform for the design of topology-specific G-quadruplex-targeting compounds and is valuable for the development of new potent anticancer drugs.
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==About this Structure==
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Solution structure of an intramolecular (3+1) human telomeric G-quadruplex bound to a telomestatin derivative.,Chung WJ, Heddi B, Tera M, Iida K, Nagasawa K, Phan AT J Am Chem Soc. 2013 Aug 2. PMID:23909929<ref>PMID:23909929</ref>
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[[2mb3]] is a 1 chain structure. Full experimental information is available from [http://oca.weizmann.ac.il/oca-bin/ocashort?id=2MB3 OCA].
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==Reference==
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From MEDLINE&reg;/PubMed&reg;, a database of the U.S. National Library of Medicine.<br>
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<ref group="xtra">PMID:023909929</ref><references group="xtra"/><references/>
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</div>
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[[Category: Chung, W J.]]
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== References ==
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[[Category: Heddi, B.]]
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<references/>
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[[Category: Iida, K.]]
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__TOC__
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[[Category: Nagasawa, K.]]
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</StructureSection>
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[[Category: Phan, A T.]]
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[[Category: Chung, W J]]
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[[Category: Tera, M.]]
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[[Category: Heddi, B]]
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[[Category: Iida, K]]
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[[Category: Nagasawa, K]]
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[[Category: Phan, A T]]
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[[Category: Tera, M]]
[[Category: Anticancer target]]
[[Category: Anticancer target]]
[[Category: Dna-dna inhibitor complex]]
[[Category: Dna-dna inhibitor complex]]

Revision as of 11:52, 18 December 2014

Solution structure of an intramolecular (3+1) human telomeric G-quadruplex bound to a telomestatin derivative

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