2qxj

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[[Image:2qxj.jpg|left|200px]]<br /><applet load="2qxj" size="350" color="white" frame="true" align="right" spinBox="true"
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[[Image:2qxj.jpg|left|200px]]
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caption="2qxj, resolution 2.10&Aring;" />
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'''Crystal Structure of Human Kallikrein 7 in Complex with Suc-Ala-Ala-Pro-Phe-chloromethylketone and Copper'''<br />
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{{Structure
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|PDB= 2qxj |SIZE=350|CAPTION= <scene name='initialview01'>2qxj</scene>, resolution 2.10&Aring;
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|SITE=
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|LIGAND= <scene name='pdbligand=CU:COPPER+(II)+ION'>CU</scene> and <scene name='pdbligand=K7J:'>K7J</scene>
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|ACTIVITY= [http://en.wikipedia.org/wiki/Stratum_corneum_chymotryptic_enzyme Stratum corneum chymotryptic enzyme], with EC number [http://www.brenda-enzymes.info/php/result_flat.php4?ecno=3.4.21.117 3.4.21.117]
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|GENE= KLK7, PRSS6, SCCE ([http://www.ncbi.nlm.nih.gov/Taxonomy/Browser/wwwtax.cgi?mode=Info&srchmode=5&id=9606 Homo sapiens])
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}}
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'''Crystal Structure of Human Kallikrein 7 in Complex with Suc-Ala-Ala-Pro-Phe-chloromethylketone and Copper'''
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==Overview==
==Overview==
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==About this Structure==
==About this Structure==
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2QXJ is a [http://en.wikipedia.org/wiki/Single_protein Single protein] structure of sequence from [http://en.wikipedia.org/wiki/Homo_sapiens Homo sapiens] with <scene name='pdbligand=CU:'>CU</scene> and <scene name='pdbligand=K7J:'>K7J</scene> as [http://en.wikipedia.org/wiki/ligands ligands]. Active as [http://en.wikipedia.org/wiki/Stratum_corneum_chymotryptic_enzyme Stratum corneum chymotryptic enzyme], with EC number [http://www.brenda-enzymes.info/php/result_flat.php4?ecno=3.4.21.117 3.4.21.117] Full crystallographic information is available from [http://oca.weizmann.ac.il/oca-bin/ocashort?id=2QXJ OCA].
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2QXJ is a [[Single protein]] structure of sequence from [http://en.wikipedia.org/wiki/Homo_sapiens Homo sapiens]. Full crystallographic information is available from [http://oca.weizmann.ac.il/oca-bin/ocashort?id=2QXJ OCA].
==Reference==
==Reference==
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Chymotryptic specificity determinants in the 1.0 A structure of the zinc-inhibited human tissue kallikrein 7., Debela M, Hess P, Magdolen V, Schechter NM, Steiner T, Huber R, Bode W, Goettig P, Proc Natl Acad Sci U S A. 2007 Oct 9;104(41):16086-91. Epub 2007 Oct 1. PMID:[http://ispc.weizmann.ac.il//pmbin/getpm?pmid=17909180 17909180]
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Chymotryptic specificity determinants in the 1.0 A structure of the zinc-inhibited human tissue kallikrein 7., Debela M, Hess P, Magdolen V, Schechter NM, Steiner T, Huber R, Bode W, Goettig P, Proc Natl Acad Sci U S A. 2007 Oct 9;104(41):16086-91. Epub 2007 Oct 1. PMID:[http://www.ncbi.nlm.nih.gov/pubmed/17909180 17909180]
[[Category: Homo sapiens]]
[[Category: Homo sapiens]]
[[Category: Single protein]]
[[Category: Single protein]]
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[[Category: K7J]]
[[Category: K7J]]
[[Category: alternative splicing]]
[[Category: alternative splicing]]
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[[Category: catalytic triad his]]
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[[Category: catalytic triad their]]
[[Category: copper]]
[[Category: copper]]
[[Category: glycoprotein]]
[[Category: glycoprotein]]
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[[Category: histidine ligands]]
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[[Category: histidine ligand]]
[[Category: hydrolase]]
[[Category: hydrolase]]
[[Category: protease]]
[[Category: protease]]
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[[Category: zymogen]]
[[Category: zymogen]]
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''Page seeded by [http://oca.weizmann.ac.il/oca OCA ] on Thu Feb 21 18:43:08 2008''
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''Page seeded by [http://oca.weizmann.ac.il/oca OCA ] on Thu Mar 20 18:30:39 2008''

Revision as of 16:30, 20 March 2008


PDB ID 2qxj

Drag the structure with the mouse to rotate
, resolution 2.10Å
Ligands: and
Gene: KLK7, PRSS6, SCCE (Homo sapiens)
Activity: Stratum corneum chymotryptic enzyme, with EC number 3.4.21.117
Coordinates: save as pdb, mmCIF, xml



Crystal Structure of Human Kallikrein 7 in Complex with Suc-Ala-Ala-Pro-Phe-chloromethylketone and Copper


Overview

hK7 or human stratum corneum chymotryptic enzyme belongs to the human tissue kallikrein (hKs) serine proteinase family and is strongly expressed in the upper layers of the epidermis. It participates in skin desquamation but is also implicated in diverse skin diseases and is a potential biomarker of ovarian cancer. We have solved x-ray structures of recombinant active hK7 at medium and atomic resolution in the presence of the inhibitors succinyl-Ala-Ala-Pro-Phe-chloromethyl ketone and Ala-Ala-Phe-chloromethyl ketone. The most distinguishing features of hK7 are the short 70-80 loop and the unique S1 pocket, which prefers P1 Tyr residues, as shown by kinetic data. Similar to several other kallikreins, the enzyme activity is inhibited by Zn(2+) and Cu(2+) at low micromolar concentrations. Biochemical analyses of the mutants H99A and H41F confirm that only the metal-binding site at His(99) close to the catalytic triad accounts for the noncompetitive Zn(2+) inhibition type. Additionally, hK7 exhibits large positively charged surface patches, representing putative exosites for prime side substrate recognition.

About this Structure

2QXJ is a Single protein structure of sequence from Homo sapiens. Full crystallographic information is available from OCA.

Reference

Chymotryptic specificity determinants in the 1.0 A structure of the zinc-inhibited human tissue kallikrein 7., Debela M, Hess P, Magdolen V, Schechter NM, Steiner T, Huber R, Bode W, Goettig P, Proc Natl Acad Sci U S A. 2007 Oct 9;104(41):16086-91. Epub 2007 Oct 1. PMID:17909180

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