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1oxa

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|PDB= 1oxa |SIZE=350|CAPTION= <scene name='initialview01'>1oxa</scene>, resolution 2.1&Aring;
|PDB= 1oxa |SIZE=350|CAPTION= <scene name='initialview01'>1oxa</scene>, resolution 2.1&Aring;
|SITE=
|SITE=
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|LIGAND= <scene name='pdbligand=HEM:PROTOPORPHYRIN+IX+CONTAINING+FE'>HEM</scene> and <scene name='pdbligand=DEB:6-DEOXYERYTHRONOLIDE B'>DEB</scene>
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|LIGAND= <scene name='pdbligand=DEB:6-DEOXYERYTHRONOLIDE+B'>DEB</scene>, <scene name='pdbligand=HEM:PROTOPORPHYRIN+IX+CONTAINING+FE'>HEM</scene>
|ACTIVITY=
|ACTIVITY=
|GENE=
|GENE=
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|DOMAIN=
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|RELATEDENTRY=
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|RESOURCES=<span class='plainlinks'>[http://oca.weizmann.ac.il/oca-docs/fgij/fg.htm?mol=1oxa FirstGlance], [http://oca.weizmann.ac.il/oca-bin/ocaids?id=1oxa OCA], [http://www.ebi.ac.uk/pdbsum/1oxa PDBsum], [http://www.rcsb.org/pdb/explore.do?structureId=1oxa RCSB]</span>
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[[Category: Cupp-Vickery, J R.]]
[[Category: Cupp-Vickery, J R.]]
[[Category: Poulos, T L.]]
[[Category: Poulos, T L.]]
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[[Category: DEB]]
 
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[[Category: HEM]]
 
[[Category: oxidoreductase (oxygenase)]]
[[Category: oxidoreductase (oxygenase)]]
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''Page seeded by [http://oca.weizmann.ac.il/oca OCA ] on Thu Mar 20 13:16:54 2008''
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''Page seeded by [http://oca.weizmann.ac.il/oca OCA ] on Sun Mar 30 22:51:40 2008''

Revision as of 19:51, 30 March 2008


PDB ID 1oxa

Drag the structure with the mouse to rotate
, resolution 2.1Å
Ligands: ,
Resources: FirstGlance, OCA, PDBsum, RCSB
Coordinates: save as pdb, mmCIF, xml



CYTOCHROME P450 (DONOR:O2 OXIDOREDUCTASE)


Overview

Cytochrome P450eryF catalyzes the 6S-hydroxylation of 6-deoxyerythronolide B, the initial reaction in a multistep pathway to convert 6-deoxyerythronolide B into the antibiotic, erythromycin. The overall structure of P450eryF is similar to that of P450cam but differs in the exact positioning of several alpha-helices. The largest difference occurs in the B' helix and results in the enlargement of the substrate-binding pocket of P450eryF. The substrate is positioned with the macrolide ring perpendicular to the haem plane and contacts seven hydrophobic residues and three solvent molecules. The substrate participates in a network of hydrogen bonds that may provide a proton shuttle pathway in the oxygen cleavage reaction.

About this Structure

1OXA is a Single protein structure of sequence from Saccharopolyspora erythraea. Full crystallographic information is available from OCA.

Reference

Structure of cytochrome P450eryF involved in erythromycin biosynthesis., Cupp-Vickery JR, Poulos TL, Nat Struct Biol. 1995 Feb;2(2):144-53. PMID:7749919

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