2pwt

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|PDB= 2pwt |SIZE=350|CAPTION= <scene name='initialview01'>2pwt</scene>, resolution 1.800&Aring;
|PDB= 2pwt |SIZE=350|CAPTION= <scene name='initialview01'>2pwt</scene>, resolution 1.800&Aring;
|SITE=
|SITE=
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|LIGAND= <scene name='pdbligand=LHA:DOUBLY FUNCTIONALIZED PAROMOMYCIN PM-II-162'>LHA</scene>
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|LIGAND= <scene name='pdbligand=A:ADENOSINE-5&#39;-MONOPHOSPHATE'>A</scene>, <scene name='pdbligand=C:CYTIDINE-5&#39;-MONOPHOSPHATE'>C</scene>, <scene name='pdbligand=G:GUANOSINE-5&#39;-MONOPHOSPHATE'>G</scene>, <scene name='pdbligand=LHA:DOUBLY+FUNCTIONALIZED+PAROMOMYCIN+PM-II-162'>LHA</scene>, <scene name='pdbligand=U:URIDINE-5&#39;-MONOPHOSPHATE'>U</scene>
|ACTIVITY=
|ACTIVITY=
|GENE=
|GENE=
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|DOMAIN=
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|RELATEDENTRY=
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|RESOURCES=<span class='plainlinks'>[http://oca.weizmann.ac.il/oca-docs/fgij/fg.htm?mol=2pwt FirstGlance], [http://oca.weizmann.ac.il/oca-bin/ocaids?id=2pwt OCA], [http://www.ebi.ac.uk/pdbsum/2pwt PDBsum], [http://www.rcsb.org/pdb/explore.do?structureId=2pwt RCSB]</span>
}}
}}
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[[Category: Szychowski, J.]]
[[Category: Szychowski, J.]]
[[Category: Westhof, E.]]
[[Category: Westhof, E.]]
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[[Category: LHA]]
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[[Category: aminoglycoside]]
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[[Category: aminoglycoside; haba group; ribosomal decoding site; x-ray analysis; rna]]
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[[Category: haba group]]
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[[Category: ribosomal decoding site]]
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[[Category: rna]]
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[[Category: x-ray analysis]]
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''Page seeded by [http://oca.weizmann.ac.il/oca OCA ] on Thu Mar 20 18:18:22 2008''
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''Page seeded by [http://oca.weizmann.ac.il/oca OCA ] on Mon Mar 31 04:41:48 2008''

Revision as of 01:41, 31 March 2008


PDB ID 2pwt

Drag the structure with the mouse to rotate
, resolution 1.800Å
Ligands: , , , ,
Resources: FirstGlance, OCA, PDBsum, RCSB
Coordinates: save as pdb, mmCIF, xml



Crystal structure of the bacterial ribosomal decoding site complexed with aminoglycoside containing the L-HABA group


Overview

The crystal structure of the complex between oligonucleotide containing the bacterial ribosomal decoding site (A site) and the synthetic paromomycin analogue 1, which contains the gamma-amino-alpha-hydroxybutyryl (L-haba) group at position N1 of ring II (2-DOS ring), and an ether chain with an O-phenethylaminoethyl group at position C2 of ring III, is reported. Interestingly, next to the paromomycin analogue 1 specifically bound to the A site, a second molecule of 1 with a different conformation is observed at the crystal packing interface which mimics the A-minor interaction between two bulged-out adenines from the A site and the codon-anticodon stem of the mRNA-tRNA complex. Improved antibacterial activity supports the conclusion that analogue 1 might affect protein synthesis on the ribosome in two different ways: 1) specific binding to the A site forces maintenance of the "on" state with two bulged out adenines, and 2) a new binding mode of 1 to an A-minor motif which stabilizes complex formation between the ribosome and the mRNA-tRNA complex regardless of whether the codon-anticodon stem is of the cognate or near-cognate type.

About this Structure

2PWT is a Protein complex structure of sequences from [1]. Full crystallographic information is available from OCA.

Reference

Crystal Structure of the Bacterial Ribosomal Decoding Site Complexed with a Synthetic Doubly Functionalized Paromomycin Derivative: a New Specific Binding Mode to an A-Minor Motif Enhances in vitro Antibacterial Activity., Kondo J, Pachamuthu K, Francois B, Szychowski J, Hanessian S, Westhof E, ChemMedChem. 2007 Nov 12;2(11):1631-1638. PMID:17722211

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