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1a70

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|RESOURCES=<span class='plainlinks'>[http://oca.weizmann.ac.il/oca-docs/fgij/fg.htm?mol=1a70 FirstGlance], [http://oca.weizmann.ac.il/oca-bin/ocaids?id=1a70 OCA], [http://www.ebi.ac.uk/pdbsum/1a70 PDBsum], [http://www.rcsb.org/pdb/explore.do?structureId=1a70 RCSB]</span>
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'''SPINACH FERREDOXIN'''
'''SPINACH FERREDOXIN'''
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[[Category: Mattevi, A.]]
[[Category: Mattevi, A.]]
[[Category: Zanetti, G.]]
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[[Category: electron transport]]
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[[Category: Electron transport]]
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[[Category: iron-sulfur protein]]
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[[Category: Iron-sulfur protein]]
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[[Category: photosynthesis]]
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Revision as of 06:54, 2 May 2008

Template:STRUCTURE 1a70

SPINACH FERREDOXIN


Overview

Ferredoxin I (Fd I) from Spinacia oleracea is composed of 97 amino-acid residues and a [2Fe-2S] cluster. The crystal structure of the E92K mutant of Fd I was solved by molecular replacement and refined to an R factor of 19.6% for 11755 reflections at 1.7 A resolution. The overall structure and the active centre of spinach Fd is highly conserved with respect to ferredoxins of known structure. The E92K mutation appears to disturb a hydrogen-bond network which stabilizes the loop bearing the [2Fe-2S] cluster. This observation provides a rationale for the reduced electron-transfer efficiency displayed by the E92K mutant. Inspection of the crystal packing reveals that the side chain of Lys92 is engaged in an intermolecular interaction with Asp26 of a symmetry-related molecule. This feature may explain why only the mutant E92K and not wild-type Fd I could be successfully crystallized.

About this Structure

1A70 is a Single protein structure of sequence from Spinacia oleracea. Full crystallographic information is available from OCA.

Reference

Structure of the mutant E92K of [2Fe-2S] ferredoxin I from Spinacia oleracea at 1.7 A resolution., Binda C, Coda A, Aliverti A, Zanetti G, Mattevi A, Acta Crystallogr D Biol Crystallogr. 1998 Nov 1;54(Pt 6 Pt 2):1353-8. PMID:10089511 Page seeded by OCA on Fri May 2 09:54:32 2008

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