User:Wayne Decatur/mof dev
From Proteopedia
(Difference between revisions)
(remove unit cell text display) |
(add JARMEU option) |
||
| Line 1: | Line 1: | ||
| + | JARMEU - a metal-organic framework | ||
| + | |||
| + | <StructureSection load='1d66' size='500' frame='true' side='right' caption='A Metal–organic framework structure: the CSD entry WUTXUH' scene='10/1092924/Csd_entry_wutxuh_basics/2' > | ||
| + | <!-- important to note you need to use 'side' in a StructureSection instead of 'align'. If you leave 'align' it doesn't work.--> | ||
| + | ==Background== | ||
| + | |||
| + | Metal-organic frameworks have been shown to be applicable to catalysis, among many other applications, as [[Proteopedia:Hot_News|highlighted three chemists doing seminal work in this field being awarded the Nobel Prize in Chemistry in 2025]]. | ||
| + | |||
| + | JARMEU... | ||
| + | |||
| + | Here the crystal structure of JARMEU metal-organic framework is featured. | ||
| + | |||
| + | ==A catalytic molybdenum metal-organic framework== | ||
| + | <jmol> | ||
| + | <jmolCheckbox> | ||
| + | <scriptWhenChecked>select all; spacefill on;</scriptWhenChecked> | ||
| + | <scriptWhenUnchecked>select all; spacefill 0.35; select hydrogen; spacefill 0.25;</scriptWhenUnchecked> | ||
| + | <checked>false</checked> | ||
| + | <!-- <checked></checked> set it to false or delete it or comment it out as <checked>false</checked> or <checked> </checked>still show as checked--> | ||
| + | <text>CPK Spacefll mode</text> | ||
| + | </jmolCheckbox> | ||
| + | </jmol> | ||
| + | |||
| + | <!--<scene name='70/701975/1d66_firstglance_secondary/2'>Each monomer</scene> of the protein dimer has 3 '''<font color='#f00080'> alpha helices</font>'''. | ||
| + | |||
| + | The protein <scene name='70/701975/1d66_firstglance/2'>binds as a dimer to a symmetrical 17-base-pair sequence</scene>. Specifically, the consensus Gal4p-binding site is a 17-mer of sequence conforming to the motif below, which has the key feature of CGG triplets at the 5' ends, separated by 11 bps, or 5′-CGG-N11-CCG-3′.<br> | ||
| + | <br>--> | ||
| + | <!--<span style="font-weight: bold;font-family: Courier New; font-size: 14pt">--> | ||
| + | <!-- By setting font to courier, I can use non-proportional font. Whereas by default, rest of Proteopedia is proportional | ||
| + | <span style="background:black;color:#FFC0C8">5'-CGGNNNNNNNNNNNCCG-3'</span><br> | ||
| + | <font style='background:black;color:#ffffff;'>|||||||||||||||||</font><br> | ||
| + | <span style="background:black;color:#FFFF80">3'-CGGNNNNNNNNNNNGGC-5'</span></span>--> | ||
| + | <br/> | ||
| + | |||
| + | <scene name='10/1092924/Csd_entry_wutxuh_set/4'>The CSD entry WUTXUH as a 1x1x3 set of the metal organic framework</scene>. | ||
| + | |||
| + | <scene name='10/1092924/Csd_entry_wutxuh_plane/4'>The CSD entry WUTXUH as a plane of the metal organic framework</scene>. | ||
| + | |||
| + | <jmol> | ||
| + | <jmolButton> | ||
| + | <script>load /wiki/scripts/10/1092924/Csd_entry_wutxuh_basics/2.spt</script> | ||
| + | <text>Restore Default Scene</text> | ||
| + | </jmolButton> | ||
| + | </jmol> | ||
| + | |||
| + | <!-- | ||
| + | <br/> | ||
| + | <br/> | ||
| + | <br/> | ||
| + | <br/> | ||
| + | --> | ||
| + | |||
| + | |||
| + | </StructureSection> | ||
| + | |||
| + | |||
| + | ==Technical Details== | ||
| + | |||
| + | The views featuring the 1x1x3 set and the plane were built using [https://chemapps.stolaf.edu/jmol/jsmol/jcse/explore.htm the Jmol Crystal Symmetry Explorer] to examine [https://www.ccdc.cam.ac.uk/structures/Search?Ccdcid=WUTXUH&DatabaseToSearch=CSD CSD Entry: WUTXUH]. | ||
| + | |||
| + | ==Reference== | ||
| + | <ref group="xtra">PMID: 32744270</ref><references group="xtra"/> | ||
| + | |||
| + | ==See also== | ||
| + | |||
| + | * [[Metal-Ligand Polyhedra]] | ||
| + | |||
| + | ----------------------- | ||
A catalytic molybdenum metal-organic framework | A catalytic molybdenum metal-organic framework | ||
Revision as of 03:46, 9 October 2025
JARMEU - a metal-organic framework
| |||||||||||
Contents |
Technical Details
The views featuring the 1x1x3 set and the plane were built using the Jmol Crystal Symmetry Explorer to examine CSD Entry: WUTXUH.
Reference
- Xia Z, Li F, Xu L, Feng P. A stable and highly selective metalloporphyrin based framework for the catalytic oxidation of cyclohexene. Dalton Trans. 2020 Aug 18;49(32):11157-11162. PMID:32744270 doi:10.1039/d0dt01420f
See also
A catalytic molybdenum metal-organic framework
| |||||||||||
Technical Details
The views featuring the 1x1x3 set and the plane were built using the Jmol Crystal Symmetry Explorer to examine CSD Entry: WUTXUH.
Reference
- Xia Z, Li F, Xu L, Feng P. A stable and highly selective metalloporphyrin based framework for the catalytic oxidation of cyclohexene. Dalton Trans. 2020 Aug 18;49(32):11157-11162. PMID:32744270 doi:10.1039/d0dt01420f
