User:Wayne Decatur/mof dev
From Proteopedia
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Synthesized metal-organic frameworks have been shown to have a wide range of applications, as [[Proteopedia:Hot_News|highlighted three chemists doing seminal work in this field being awarded the Nobel Prize in Chemistry in 2025]]. | Synthesized metal-organic frameworks have been shown to have a wide range of applications, as [[Proteopedia:Hot_News|highlighted three chemists doing seminal work in this field being awarded the Nobel Prize in Chemistry in 2025]]. | ||
| - | Here the crystal structure of a cubic diamond metal-organic framework is featured; [https://www.ccdc.cam.ac.uk/structures/Search?Ccdcid=JARMEU&DatabaseToSearch=CSD the CSD entry JARMEU]. This is the structure that | + | Here the crystal structure of a cubic diamond metal-organic framework is featured; [https://www.ccdc.cam.ac.uk/structures/Search?Ccdcid=JARMEU&DatabaseToSearch=CSD the CSD entry JARMEU]. This is the structure that revealed that a crystalline, diamondoid, extended framework was formed that had large cavities, establishing this class of solid polymeric materials. |
==A cubic diamond lattice metal-organic framework== | ==A cubic diamond lattice metal-organic framework== | ||
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<br/> | <br/> | ||
| - | + | The page starts with the building block shown. | |
| - | The large cavities are visible as the lattice layers onto itself as the view of the structure rotates. | + | <scene name='10/1092924/Csd_entry_jarmeu_1x1x3_set/3'>The CSD entry JARMEU as a 1x1x3 set of the metal organic framework</scene>.<br/> |
| + | It a beautiful diamondoid structure that is a 4-connected network. <br/> | ||
| + | The large cavities are visible as the lattice layers onto itself as the view of the structure rotates. <br/> | ||
<scene name='10/1092924/Csd_entry_jarmeu_1x3x3_plane/2'>The CSD entry JARMEU as a 1x3x3 plane of the metal organic framework</scene>. (Patience required when loading this view.) | <scene name='10/1092924/Csd_entry_jarmeu_1x3x3_plane/2'>The CSD entry JARMEU as a 1x3x3 plane of the metal organic framework</scene>. (Patience required when loading this view.) | ||
Revision as of 18:41, 9 October 2025
A cubic diamond lattice metal-organic framework
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Contents |
Technical Details
The views featuring the 1x1x3 set and the plane were built using the Jmol Crystal Symmetry Explorer to examine CSD Entry: JARMEU.
Reference
- B.F. Hoskins and R. Robson. 1989. Infinite polymeric frameworks consisting of three dimensionally linked rod-like segments. Journal of the American Chemical Society, v111, pg. 5962-5964, |DOI: 10.1021/ja00197a079
See also
A catalytic molybdenum metal-organic framework
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Technical Details
The views featuring the 1x1x3 set and the plane were built using the Jmol Crystal Symmetry Explorer to examine CSD Entry: WUTXUH.
Reference
- Xia Z, Li F, Xu L, Feng P. A stable and highly selective metalloporphyrin based framework for the catalytic oxidation of cyclohexene. Dalton Trans. 2020 Aug 18;49(32):11157-11162. PMID:32744270 doi:10.1039/d0dt01420f
