User:Wayne Decatur/mof dev

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The metal here is copper.
When the repeats of this building block are shown connected to others, the lattice appears. Viewing the <scene name='10/1092924/Csd_entry_jarmeu_1x1x3_set/3'>the CSD entry JARMEU as a 1x1x3 set of the metal organic framework</scene> illustrates this.<br/>
When the repeats of this building block are shown connected to others, the lattice appears. Viewing the <scene name='10/1092924/Csd_entry_jarmeu_1x1x3_set/3'>the CSD entry JARMEU as a 1x1x3 set of the metal organic framework</scene> illustrates this.<br/>
When considered this way a beautiful diamondoid structure appears that is a 4-connected network. <br/>
When considered this way a beautiful diamondoid structure appears that is a 4-connected network. <br/>
The large cavities are visible as the lattice layers onto itself as the view of the structure rotates. <br/>
The large cavities are visible as the lattice layers onto itself as the view of the structure rotates. <br/>
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The cavities would contain anions and solvent that are not shown in this crystal structure as they'd be freely moving and randomly distributed.
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The extensive nature of the lattice with the large catvities becomes more apparent if we consider more of the repeated building blocks. <br/>
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The extensive nature of the network with the large cavities becomes more apparent if we consider more of the repeated building blocks. <br/>
<scene name='10/1092924/Csd_entry_jarmeu_1x3x3_plane/2'>The CSD entry JARMEU as a 1x3x3 plane of the metal organic framework</scene>. (Substatntial patience required when loading this scene; it is suggested to only do that after you have examined the others.)
<scene name='10/1092924/Csd_entry_jarmeu_1x3x3_plane/2'>The CSD entry JARMEU as a 1x3x3 plane of the metal organic framework</scene>. (Substatntial patience required when loading this scene; it is suggested to only do that after you have examined the others.)

Revision as of 19:24, 9 October 2025

A Metal–organic framework structure: the CSD entry JARMEU

Drag the structure with the mouse to rotate

Contents

Technical Details

The views featuring the 1x1x3 set and the plane were built using the Jmol Crystal Symmetry Explorer to examine CSD Entry: JARMEU.

Reference

  • B.F. Hoskins and R. Robson. 1989. Infinite polymeric frameworks consisting of three dimensionally linked rod-like segments. Journal of the American Chemical Society, v111, pg. 5962-5964, |DOI: 10.1021/ja00197a079

See also




A catalytic molybdenum metal-organic framework

A Metal–organic framework structure: the CSD entry WUTXUH

Drag the structure with the mouse to rotate


Technical Details

The views featuring the 1x1x3 set and the plane were built using the Jmol Crystal Symmetry Explorer to examine CSD Entry: WUTXUH.

Reference

  • Xia Z, Li F, Xu L, Feng P. A stable and highly selective metalloporphyrin based framework for the catalytic oxidation of cyclohexene. Dalton Trans. 2020 Aug 18;49(32):11157-11162. PMID:32744270 doi:10.1039/d0dt01420f

See also

Proteopedia Page Contributors and Editors (what is this?)

Wayne Decatur

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