Cubic Diamond Lattice Metal-Organic Framework
From Proteopedia
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When the repeats of this 4-connected network building block are shown connected to others, the crystalline lattice appears.<br/> | When the repeats of this 4-connected network building block are shown connected to others, the crystalline lattice appears.<br/> | ||
- | Viewing the <scene name='10/1092924/Csd_entry_jarmeu_1x1x3_set/4'>the CSD entry JARMEU as a | + | Viewing the <scene name='10/1092924/Csd_entry_jarmeu_1x1x3_set/4'>the CSD entry JARMEU as a 1x3x3 set of the metal organic framework</scene> illustrates this.<br/> |
The large cavities are visible as the lattice layers onto itself as the view of the structure rotates. <br/> | The large cavities are visible as the lattice layers onto itself as the view of the structure rotates. <br/> | ||
The cavities would contain anions and solvent that are not shown in this crystal structure as they'd be freely moving and randomly distributed. | The cavities would contain anions and solvent that are not shown in this crystal structure as they'd be freely moving and randomly distributed. | ||
The extensive crystalline nature with the large cavities becomes more apparent if we consider more of the repeated building blocks. <br/> | The extensive crystalline nature with the large cavities becomes more apparent if we consider more of the repeated building blocks. <br/> | ||
- | <scene name='10/1092924/ | + | <scene name='10/1092924/Csd_entry_jarmeu_lattice/4'>The CSD entry JARMEU as a 1x4x6 lattice of the metal organic framework</scene>. |
+ | |||
+ | <scene name='10/1092924/Csd_entry_jarmeu_lattice/5'>Restrict to only the central cell of the 1x4x6 lattice</scene>. | ||
+ | <jmol> | ||
+ | <jmolCheckbox> | ||
+ | <scriptWhenChecked>display all;</scriptWhenChecked> | ||
+ | <scriptWhenUnchecked>restrict cell=555;</scriptWhenUnchecked> | ||
+ | <checked>false</checked> | ||
+ | <!-- <checked></checked> set it to false or delete it or comment it out as <checked>false</checked> or <checked> </checked>still show as checked--> | ||
+ | <text>Toggle back on lattice</text> | ||
+ | </jmolCheckbox> | ||
+ | </jmol> | ||
<jmol> | <jmol> | ||
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</StructureSection> | </StructureSection> | ||
+ | |||
==References== | ==References== | ||
<references/> | <references/> |
Revision as of 19:26, 12 October 2025
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References
- ↑ B.F. Hoskins and R. Robson. 1989. Infinite polymeric frameworks consisting of three dimensionally linked rod-like segments. Journal of the American Chemical Society, v111, pg. 5962-5964, |DOI: 10.1021/ja00197a079
- ↑ https://www.nobelprize.org/uploads/2025/10/advanced-chemistryprize2025.pdf