2eb8

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[[Image:2eb8.jpg|left|200px]]
[[Image:2eb8.jpg|left|200px]]
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{{Structure
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|PDB= 2eb8 |SIZE=350|CAPTION= <scene name='initialview01'>2eb8</scene>, resolution 1.65&Aring;
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The line below this paragraph, containing "STRUCTURE_2eb8", creates the "Structure Box" on the page.
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|SITE=
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|LIGAND= <scene name='pdbligand=CUP:(N-SALICYLIDEN-L-PHENYLALANATO)-COPPER(II)'>CUP</scene>, <scene name='pdbligand=PO4:PHOSPHATE+ION'>PO4</scene>
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{{STRUCTURE_2eb8| PDB=2eb8 | SCENE= }}
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|RELATEDENTRY=[[2eb9|2EB9]]
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|RESOURCES=<span class='plainlinks'>[http://oca.weizmann.ac.il/oca-docs/fgij/fg.htm?mol=2eb8 FirstGlance], [http://oca.weizmann.ac.il/oca-bin/ocaids?id=2eb8 OCA], [http://www.ebi.ac.uk/pdbsum/2eb8 PDBsum], [http://www.rcsb.org/pdb/explore.do?structureId=2eb8 RCSB]</span>
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'''Crystal Structure of Cu(II)(Sal-Phe)/apo-Myoglobin'''
'''Crystal Structure of Cu(II)(Sal-Phe)/apo-Myoglobin'''
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[[Category: Watanabe, Y.]]
[[Category: Watanabe, Y.]]
[[Category: Yamane, T.]]
[[Category: Yamane, T.]]
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[[Category: oxygen storage/transport]]
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[[Category: Oxygen storage/transport]]
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''Page seeded by [http://oca.weizmann.ac.il/oca OCA ] on Sun May 4 02:16:13 2008''
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''Page seeded by [http://oca.weizmann.ac.il/oca OCA ] on Mon Mar 31 02:46:28 2008''
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Revision as of 23:16, 3 May 2008

Image:2eb8.jpg

Template:STRUCTURE 2eb8

Crystal Structure of Cu(II)(Sal-Phe)/apo-Myoglobin


Overview

apo-Myoglobin (apo-Mb) was reconstituted with three copper complexes: CuII(Sal-Phe) (1; Sal-Phe = N-salicylidene-L-phenylalanato), CuII(Sal-Leu) (2; Sal-Leu = N-salicylidene-L-leucinato), and CuII(Sal-Ala) (3; Sal-Ala = N-salicylidene-L-alanato). The crystal structures of 1.apo-Mb (1.65 Angstrom resolution) and 2.apo-Mb (1.8 Angstrom resolution) show that the coordination geometry around the CuII atom in apo-Mb is distorted square-planar with tridentate Sal-X and a Nepsilon atom of His64 in the apo-Mb cavity and the plane of these copper complexes is perpendicular to that of heme. These results suggest that the apo-Mb cavity can hold metal complexes with various coordination geometries.

About this Structure

2EB8 is a Single protein structure of sequence from Physeter catodon. Full crystallographic information is available from OCA.

Reference

Design and structure analysis of artificial metalloproteins: selective coordination of His64 to copper complexes with square-planar structure in the apo-myoglobin scaffold., Abe S, Ueno T, Reddy PA, Okazaki S, Hikage T, Suzuki A, Yamane T, Nakajima H, Watanabe Y, Inorg Chem. 2007 Jun 25;46(13):5137-9. Epub 2007 May 25. PMID:17523632 Page seeded by OCA on Sun May 4 02:16:13 2008

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