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Function(s) and Biological Relevance
Tetrahydroprotoberberine N-methyltransferase (TNMT) catalyzes the N-methylation of (S)-stylopine in the pathway leading to protopines and benzo [c] phenanthridines. Also acts on (S) - canadine in a different pathway that leads to the production of phthalideisoquinolines. The substrate specificity of TNMT enzymes appears to arise from the arrangement of subgroup- specific stereospecific recognition elements relative to catalytic elements that are more widely- conserved.
Broader Implications
Structural highlights and structure-function relationships
Energy Transformation
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