Structural highlights
Publication Abstract from PubMed
Metal coordination and peptide-directed self-assembly are two proven methods for creating defined supramolecular architectures. Here, we report a new class of crystalline materials based on coiled-coil peptides bearing unnatural metal-chelating terpyridine moieties. High-resolution structural characterization of lattices formed in the presence of Cu2+ reveals a general assembly mechanism. Subtle sequence variation in the modular synthetic ligand dictates assembly morphology.
Supramolecular Metal-Coordination Polymers, Nets, and Frameworks from Synthetic Coiled-Coil Peptides.,Tavenor NA, Murnin MJ, Horne WS J Am Chem Soc. 2017 Feb 15;139(6):2212-2215. doi: 10.1021/jacs.7b00651. Epub 2017, Feb 7. PMID:28161945[1]
From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine.
References
- ↑ Tavenor NA, Murnin MJ, Horne WS. Supramolecular Metal-Coordination Polymers, Nets, and Frameworks from Synthetic Coiled-Coil Peptides. J Am Chem Soc. 2017 Feb 15;139(6):2212-2215. doi: 10.1021/jacs.7b00651. Epub 2017, Feb 7. PMID:28161945 doi:http://dx.doi.org/10.1021/jacs.7b00651
